Premarital sexual intercourse is not a kinyan unless it is done with the intention of being koneh. Not only that, but the man must say as much. Rambam Hil Ishus 3:5 (my own translation):
ואם קידש בביאה אומר לה הרי את מקודשת לי או הרי את מאורסת לי או הרי את לי לאשה בבעילה זו וכל כיוצא בזה. ומתייחד עמה בפני שני עדים ובועלה
If he betroths (mekadesh) with sexual relations, he says "Behold, you are betrothed (mekudeshet) to me", or "Behold, you are married (me'ureset) to me", or "Behold, you are a wife to me with this intercourse", or anything of that sort. He secludes himself with her before two witnesses and copulates with her.
Now, the seclusion works because there are witnesses and because they know that his intention is for marriage. (See Maggid Mishna.) If there's no witnesses, there's no kiddushin.
As a side note, there is a separate prohibition against premarital sex. See Rambam Hil. Ishus 1:4.