Did the Jews make a Bracha on eating the Mahn? Which Bracha did they make?
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The sefer כמוצא שלל רב has several articles on it.
He quotes R' Yehuda Hechosid as specifying "HaMotzi Lechem Min HaShamayim" together with the Rama of Fano. Rav Tzvi Hirsch from Ziditschov quotes the mekubal R' Yisroel Dov that no brocho is to be made as mentioned anonymously in the Shut Torah Lishma 63.
Rav Aharon Levi from Reisha supports this view. The Bnei Yisoschor suggests that if it were not for the opinion of the Rama of Fano, he would have said no brocho on weekdays and "asher kideshonu bemitzvosov le'echol seudas Shabbos" on Shabbos.
Rabbi Chaim Pelagi (בספר נפש חיים מערכת מ' אות קו) from Izmir suggests "borei minei mezonos" because the mahn tasted like wafers with honey; but since they fixed their meal on it (not having any other "bread") the brocho was hamotzi.
Rabbi Eliezer Deutsch from Banihad (?) suggests that the brocho would depend on what food the eater intended. Rav Osher Weiss shlit"o points out that this depends on whether the mahn actually changed into the food imagined by the eater or just tasted like it.
There's much more in the sefer.
Shut Torah Lishma 63 (h/t Alex for the link) quotes the Rama of Fano as saying that the bracha was HaMotzi Lechem Min HaShamayim. He personally thinks the bracha is HaMamtir Lechem Min HaShamayim following the words of the pasuk that describe the man falling. Note also that the questioner in the responsa quotes "a rabbi" who claimed that no bracha was said on the man.
The Talmud (Berachot 48b) says that Moshe established the first bracha of bentching (HaZan) when the man fell, so presumably they said that after eating the man.
Sforno (to Ex. 16:27) states that the people who attempted to gather man on Shabbos would thereby have performed the forbidden labor of oker (uprooting something from the place where it grows), a subdivision of kotzer (reaping). A marginal note in the Me'oros (Gurary) edition of Berachos (48b) cites this and points out that this implies that it could indeed be considered an earth-grown product to the extent of getting the usual berachah for such - i.e., hamotzi lechem min ha-aretz.